Untitled Document
The Mystery of the Missing Solar Wind Oxygen in Lunar
Soil\
Trevor Ireland1, Michelle Bannister2, and Masahiko Honda1
1 Research School of Earth Sciences, Australian National University, Canberra,
ACT 0200, Australia
2 Research School of Astronomy and Astrophysics, Australian
National University, Canberra, ACT 0200, Australia
We have previously reported an isotopically heavy component
(5% enriched in 17O and 18O) in the lunar soil that is preserved in the
top few hundred nanometers of lunar metal grains. The location
of this component appears consistent with the site expected for solar
wind oxygen. However,
McKeegan and colleagues reported at the Lunar and Planetary Science Conference
this year that solar wind appears enriched in 16O. We have carried
out measurements on a larger number of grains from a variety of soils
in an attempt to elucidate this discrepancy. Many more grains have
been discovered with 17O 18O enrichments with
surprisingly few having 16O-rich compositions, and none around the 6%
enriched composition reported by McKeegan et al. (2008). Further
analyses by Hashizume and Chaussidon (2008) also reveal 17O,
18O-rich
compositions in modern lunar soils, while 16O rich compositions in ancient
soils are typically mass-dependently fractionated. The question
then arises, what happened to the solar wind oxygen on the surface of
the Moon.
We have measured Ne isotopic compositions in olivine grains from the
lunar soils and these are consistent with solar wind implantation. It
should therefore be expected that solar wind oxygen should be present
in the surfaces of these grains. We cannot measure olivine grains
for implanted solar-wind oxygen because of the high intrinsic concentration
of oxygen in olivine. The issue is either the high density of the
lunar metals biasing metal grains from exposure to the solar wind, or
an issue of preservation. To address this, we will attempt to measure
Ne in these metal grains to ascertain their exposure history. The
solar wind exposure takes place at lunar surface temperatures of around
100°C. At such temperatures, oxygen diffusion is probably a major
issue in retention in the lunar grains, particularly with the high flux
of hydrogen carried by the solar wind. These issues will be examined
with experiments on oxygen diffusion in metals under appropriate physical
conditions.
While solar wind appears poorly represented in the metal grains, the
component enriched in 17O and 18O is quite widespread. This component
may be carried in cometary water, which is expected to have an isotopically
heavy composition. The preservation of this component may be related
to subsurface reaction of water with Fe metal.